taken from chevy high performance.
http://www.chevyhiperformance.com/techarticles/74058_carburetor_valve_problems/index.html
What It Does
Most carburetors employ what is generally called a power valve circuit. This circuit enriches the air-fuel mixture when the carburetor goes to wide-open throttle (WOT). At WOT, intake manifold vacuum drops to almost zero. When this occurs, the power valve opens and directs more fuel into the main power circuit, in addition to fuel delivered by the main jets. The Holley power valve employs a small rubber diaphragm that is opened by a small coil spring. The valve is held closed whenever sufficient engine vacuum is present. At WOT, engine vacuum disappears and the power valvespring opens the valve, directing fuel through a small, precise orifice in the metering block called the power valve channel restrictor. This restrictor determines the amount of additional fuel delivered to the engine.
Power valves are used most frequently on the primary side of a Holley carburetor. They allow the carburetor to operate with much leaner main circuit jetting for part-throttle fuel economy. Then, when the throttle is slammed open, the power valve adds additional fuel, creating the rich air-fuel ratio needed for WOT operation. Most Holley power valve circuits are designed to add the equivalent of 8 to 10 jet sizes of additional fuel. Holley does offer a power valve block-off part that closes the power valve circuit, but this means the jet size must be increased in order to compensate for the lost power valve circuit fuel. Imagine how bad your fuel mileage would be if you had to add 10 jet sizes to the primary side of your carburetor!